Disclaimer: I've seen all of them except Brosnan's last three - so I'll update this when I finish up.
Movies:
1. Goldfinger
2. The Spy Who Loved Me
3. Goldeneye
4. Casino Royale
5. You Only Live Twice
Main Villains:
1. Goldfinger
2. Scaramanga (The Man with the Golden Gun)
3. Blofeld (On Her Majesty's Secret Service)
4. Stromberg (The Spy Who Loved Me)
5. Dr. No
Villain Henchmen/Henchwomen:
1. Red Grant (From Russia with Love)
2. Oddjob (Goldfinger)
3. Jaws (The Spy Who Loved Me)
4. Tee Hee (Live and Let Die)
5. Nick Nack (The Man with the Golden Gun)
Bond Girls:
1. Di Vicenzo (On Her Majesty's Secret Service)
2. Goodnight (The Man With the Golden Gun)
3. Amasova (The Spy Who Loved Me)
4. Natalya (Goldeneye)
5. Romanova (From Russia with Love)
I'll be honest I don't care for any of the songs except Skyfall and Live and Let Die.
Actor Rank:
1. Connery
2. Moore
3. Brosnan
4. Craig
5. Lazenby
6. Dalton